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Kinetica
Aug 16, 2011

GenericOverusedName posted:

A lot of chemical names are basically just german compound words that describe the structure, if it follows standard naming conventions. Hardest part for that compound is the first part on the right, isowurtzitane. It is describing the shape of the weird carbon cage, but that's not something you run into often like an propyl group or whatever so it's a weird word for a weird cage. After that you have hexa (6) aza (aromatic nitrogen stuff), so six nitrogens in that cage structure replacing some of the carbons, and then hexa (6) nitro groups attached to it.

TNT is short for trinitrotoluene. It's a toluene (a benzene with a methyl group on it, IUPAC name would be 'methylbenzene' but TNT predates that common usage) with three nitro groups on it.

Problem is a lot of earlier chemistry was figured out before we figured out a standardized way (or two) of describing chemicals. A lot of things have weird names as a result.

I always remember isowurtzitane because one of my Ochem teachers was a dick and put it on the first test.

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Hexyflexy
Sep 2, 2011

asymptotically approaching one

Kinetica posted:

I always remember isowurtzitane because one of my Ochem teachers was a dick and put it on the first test.

1-diazidocarbamoyl-5-azidotetrazole

No. No. No. gently caress you. I've done a little bit of computational chemistry in my life and I can't think how the gently caress that thing works.

"Bond Angles", they're just a theory dude.

LupusAter
Sep 5, 2011

Rigged Death Trap posted:

Its mainly intesting for the above reason.
Its an incredibly, incredibly useful solvent. I'm loathe to call it a universal solvent but it comes close.

It's also a pain in the rear end to get dry, we had to run two separate distillations over sodium, with all the fun of having to switch the boiler flasks from under the drying apparatuses when we needed to refill the pre-dry one. And the fact that it's perfecly mixable with water can mess with extractions.

Chitin
Apr 29, 2007

It is no sign of health to be well-adjusted to a profoundly sick society.

Mustached Demon posted:

Fine. Chug the HF. Drink it down until you no longer have teeth. Or bones.

Ow oof ouch

Code Jockey
Jan 24, 2006

69420 basic bytes free

Chitin posted:

Ow oof ouch

Nice. :golfclap:

Zemyla
Aug 6, 2008

I'll take her off your hands. Pleasure doing business with you!

Chitin posted:

Ow oof ouch

Thank :skeltal: for calcium gluconate!

Sagebrush
Feb 26, 2012

ERM... Actually I have stellar scores on the surveys, and every year students tell me that my classes are the best ones they’ve ever taken.

Phanatic posted:

I lot of them have weird names *because* we figured out a standardized way of describing chemicals.

https://en.wikipedia.org/wiki/Nonanal

some of my favorite weird chemical names:

https://en.wikipedia.org/wiki/Uranate
https://en.wikipedia.org/wiki/Arsole
https://en.wikipedia.org/wiki/Psicose
https://en.wikipedia.org/wiki/Thebacon
https://en.wikipedia.org/wiki/Squaric_acid
https://en.wikipedia.org/wiki/Moronic_acid
https://en.wikipedia.org/wiki/Penguinone
https://en.wikipedia.org/wiki/Megaphone_(molecule)
https://en.wikipedia.org/wiki/Cadaverine and the related https://en.wikipedia.org/wiki/Putrescine

Bogatyr
Jul 20, 2009
I think this belongs here.

http://mtstandard.com/natural-resou...26b8e4ba41.html

SLOSifl
Aug 10, 2002


It sounds perfectly safe...they said there is at least two feet of sludge on top to prevent fires. I don't know but that sounds like plenty of sludge, right?

ullerrm
Dec 31, 2012

Oh, the network slogan is true -- "watch FOX and be damned for all eternity!"

Sagebrush posted:

some of my favorite weird chemical names:

I think my favorite silly chemical name is still BARF -- it's an anion used to create some engineering plastics. (A single boron atom surrounded by four fluorinated aryl groups in a tetrahedron, hence [BArF4]-)

Memento
Aug 25, 2009


Bleak Gremlin

ullerrm posted:

I think my favorite silly chemical name is still BARF -- it's an anion used to create some engineering plastics. (A single boron atom surrounded by four fluorinated aryl groups in a tetrahedron, hence [BArF4]-)

Cassiterite (tin ore) has the chemical formula SnO2, or snot if you're nasty.

Collateral Damage
Jun 13, 2009

ullerrm posted:

I think my favorite silly chemical name is still BARF -- it's an anion used to create some engineering plastics. (A single boron atom surrounded by four fluorinated aryl groups in a tetrahedron, hence [BArF4]-)
Please tell me it smells really bad too.

Bogatyr
Jul 20, 2009

SLOSifl posted:

It sounds perfectly safe...they said there is at least two feet of sludge on top to prevent fires. I don't know but that sounds like plenty of sludge, right?

It sounds like the sludge is the White Phosphorous. So it's water and plastic balls on top of the sludge. I put this here since I am the furthest thing from a chemist. I am inclined to believe the potential worst case possibility. I am also open to possibility that this stuff has been sitting out in the weather for so long that it's contaminated with enough dirt and whatnot that it might just be a toxic hellhole and not a flammable toxic hellhole.

Mustached Demon
Nov 12, 2016

Can we throw Scott Pruitt in there? He seems to prefer super fund style reaction to pollution prevention after all.

Beepity Boop
Nov 21, 2012

yay

Bogatyr posted:

It sounds like the sludge is the White Phosphorous. So it's water and plastic balls on top of the sludge. I put this here since I am the furthest thing from a chemist. I am inclined to believe the potential worst case possibility. I am also open to possibility that this stuff has been sitting out in the weather for so long that it's contaminated with enough dirt and whatnot that it might just be a toxic hellhole and not a flammable toxic hellhole.

quote:

Just sampling the concrete tank's contents started fires that couldn't be extinguished with water until the phosphorus in the sludge samples burned up.

Gonna go with a solid "no" on that one.

Dirt Road Junglist
Oct 8, 2010

We will be cruel
And through our cruelty
They will know who we are

Typical Butte. Recognized the newspaper before I even clicked the link. The whole town is a giant Superfund site, and most of the bodies of standing water have to have bird deterents because it's not unusual for a flock of migrating geese or whatever to dissolve en masse in the Berkeley Pit every few seasons.

But don't worry if you visit. They pump the drinking water in from an aquifer on the other side of the mountains. Also, get the fried pork chop sandwich. Just trust me on that. Goddamn, now I wanna go to Butte, and I totally could have last week. Missed opportunity for a casually racist fried meat sammich and some quality OSHA.txt pics for my Instagram.

zedprime
Jun 9, 2007

yospos
Of course Butte is full of poo poo.

Beepity Boop
Nov 21, 2012

yay

DirtRoadJunglist posted:

Typical Butte. Recognized the newspaper before I even clicked the link. The whole town is a giant Superfund site, and most of the bodies of standing water have to have bird deterents because it's not unusual for a flock of migrating geese or whatever to dissolve en masse in the Berkeley Pit every few seasons.

But don't worry if you visit. They pump the drinking water in from an aquifer on the other side of the mountains. Also, get the fried pork chop sandwich. Just trust me on that. Goddamn, now I wanna go to Butte, and I totally could have last week. Missed opportunity for a casually racist fried meat sammich and some quality OSHA.txt pics for my Instagram.

:stonklol: You, uh...you wanna expand on that part a bit?

crazypeltast52
May 5, 2010



https://en.m.wikipedia.org/wiki/Berkeley_Pit

It's an old open pit mine that was shuttered, but the water is so acidic that it is very not good for anything living around it. There are actually such high levels of dissolved metals that they can mine the water for copper.

It is still a couple decades before the water in the pit gets high enough to hit groundwater, but it will be there soon if it doesn't get treated somehow.

Kazinsal
Dec 13, 2011

Hremsfeld posted:

:stonklol: You, uh...you wanna expand on that part a bit?

The Berkeley Pit is filled with highly acidic water that also contains high concentrations of heavy metals and other unpleasant chemicals such as arsenic and sulfuric acid. It continues to get worse naturally because the water in the pit is slowly dissolving the rock around it, leeching more terrible things into the water.

The chemicals kill the geese. The water just dissolves the corpses.

My Lovely Horse
Aug 21, 2010

crazypeltast52 posted:

It is still a couple decades before the water in the pit gets high enough to hit groundwater, but it will be there soon if it doesn't get treated somehow.
You say expensive water treatment, I'm hearing mineral water business.

Beepity Boop
Nov 21, 2012

yay

I shouldn't be surprised, considering what thread this is, but I guess there's a big mental difference between "yeah don't touch this if you like your limbs, but don't be a dumbass and nothing bad will happen" and "this is currently and actively causing living things to dissolve out there in the real world." Thanks!

Vitamins
May 1, 2012


My Lovely Horse posted:

You say expensive water treatment, I'm hearing mineral water business.

"Contains 1000x the doctor recommended daily dose of copper!" :pseudo:

Dirt Road Junglist
Oct 8, 2010

We will be cruel
And through our cruelty
They will know who we are
I posted a bit about the Pit, and Butte in general, in the Montana thread a while back:
https://forums.somethingawful.com/showthread.php?threadid=3822630#post473013024

With bonus pictures! Yes, it's that color. It's much more intense if you fly over, because you get a real sense of how deep it is. Literally looks like a gash in the earth that's full of blood.



The most recent geese-kill was last winter. Something like 10,000 birds were killed, and there was a state-wide warning not to eat any wild goose-flesh and to deliver any carcasses to the state for necropsies. A goose was taken to a veterinarian in reasonably good health, but died a few days later.

Whatever's in the water is generally fatal to most living things, never mind that it's so acidic that it ate the last boat ramp a while back and they haven't been able to put anything on the water since. Made collecting the goose caracasses a loving chore. If I remember right, they had to swap boats out after a few hours anyway, otherwise the hulls would get eaten through. Oh, but there are nematodes that thrive in that toxic slop! Last I heard, they're being researched for potential cancer fighting agents. Life finds a way...

darthbob88
Oct 13, 2011

YOSPOS

DirtRoadJunglist posted:

Whatever's in the water is generally fatal to most living things, never mind that it's so acidic that it ate the last boat ramp a while back and they haven't been able to put anything on the water since. Made collecting the goose caracasses a loving chore. If I remember right, they had to swap boats out after a few hours anyway, otherwise the hulls would get eaten through. Oh, but there are nematodes that thrive in that toxic slop! Last I heard, they're being researched for potential cancer fighting agents. Life finds a way...
Yeah, and apparently they're also being investigated as a way to extract the metal from the water.

Memento
Aug 25, 2009


Bleak Gremlin
Turns out, mining is bad.

There's a mine in Queensland, lead/zinc/silver, that closed down in 2015 as it was played out. I was chatting with one of the enviro engineers at that company a few weeks ago and the rehab they're scheduled to do under Australian law is going to cost them basically as much money as they made by working the mine for the six~ years they owned it.

They bought it in 2009 with the understanding that they could expand it quite a bit. Then a Native Title claim turned up and put an end to those plans. It's probably going to drive them bankrupt.

Mustached Demon
Nov 12, 2016

Memento posted:

Turns out, mining is bad.

There's a mine in Queensland, lead/zinc/silver, that closed down in 2015 as it was played out. I was chatting with one of the enviro engineers at that company a few weeks ago and the rehab they're scheduled to do under Australian law is going to cost them basically as much money as they made by working the mine for the six~ years they owned it.

They bought it in 2009 with the understanding that they could expand it quite a bit. Then a Native Title claim turned up and put an end to those plans. It's probably going to drive them bankrupt.

Galena ores neato though.

Minings not too bad, relatively, if they include plans to deal with waste as it's created instead of just plopping in a pond for the EPA or whoever to clean up. It's still incredibly bad for the environment but metals needed for internet porn.

Dirt Road Junglist
Oct 8, 2010

We will be cruel
And through our cruelty
They will know who we are

Mustached Demon posted:

It's still incredibly bad for the environment but metals needed for internet porn.

I always had a good chuckle at the guy who parked down the street from me and had a, "BAN MINING" sticker...on his car.

Almost as funny as the big fucker pickup parked by Papa John's with "PLUMTITS" in purple fantasy script across the top of the windshield.

McSpergin
Sep 10, 2013

The site I'm working on at the moment has hectic environmental stuff. Like if there's a chemical spill (we only really use diesel and hydraulic oil on site being roadworks) on the alignment or any part of the site they have to stop work, remove the dirt until they find clean earth in all directions, go a bit further, then refill with clean earth. It can be painful like when there was a 200L oil spill the other week it cost us half a day all because a hose blew on a scraper

Memento
Aug 25, 2009


Bleak Gremlin

McSpergin posted:

The site I'm working on at the moment has hectic environmental stuff. Like if there's a chemical spill (we only really use diesel and hydraulic oil on site being roadworks) on the alignment or any part of the site they have to stop work, remove the dirt until they find clean earth in all directions, go a bit further, then refill with clean earth. It can be painful like when there was a 200L oil spill the other week it cost us half a day all because a hose blew on a scraper

https://www.youtube.com/watch?v=gGbuzBBWHcI
https://www.youtube.com/watch?v=jtdoSqPBjEQ

McSpergin
Sep 10, 2013


Neat! I'm new to the civil construction game being a mech eng but it's been a learning experience. For example, my day yesterday involved supervising this 64m multi combination (4 of) getting up a 10% incline to site. Fun times! We also have a 280T crawler crane on site lifting the 90T girders. These are only small but it's all new :)

Yawgmoth
Sep 10, 2003

This post is cursed!

DirtRoadJunglist posted:

Almost as funny as the big fucker pickup parked by Papa John's with "PLUMTITS" in purple fantasy script across the top of the windshield.
This reminds me: saw a white panel van with the custom license plate CANDYMAN at the grocery store a while ago. To this day it is the only vanity license plate I have respected.

rndmnmbr
Jul 3, 2012

babyeatingpsychopath posted:

TBH, the whole TATP preparation is a bunch of fun.

TATP is called the Mother of Satan for a reason.

babyeatingpsychopath
Oct 28, 2000
Forum Veteran


rndmnmbr posted:

TATP is called the Mother of Satan for a reason.

With good glassware and lab setup, it's far less irritating than HMX or RDX. Not nearly as fussy as nitrating (tolulene, glycerin, cellulose), and far, far less messy than picric acid. Of all the stuff we had to make, TATP was the most fun and least "critical."

RedneckwithGuns
Mar 28, 2007

Up Next:
Fifteen Inches of
SHEER DYNAMITE


Now that just makes me want to go back and find the review paper I did on those types of extremophiles in undergrad. Friggin' bacteria in heavy metal mining waste that could make armor (proteinaceous shell) out of things like gold, lead, even a case where it happened with uranium.

EDIT: from a post I did last year actually:

RedneckwithGuns posted:

This is in response to the poster asking about ways microbes deal with environmental contaminants like heavy metals a bit ago, but I finally found this paper I cited a few years ago about a strain of B. sphaericus that uses heavy metals to literally make armor for itself

http://www.ncbi.nlm.nih.gov/pubmed/16005595

Of course it was found in uranium mine tailings which makes it even more :black101:

RedneckwithGuns has a new favorite as of 23:43 on Jun 21, 2017

Dirt Road Junglist
Oct 8, 2010

We will be cruel
And through our cruelty
They will know who we are

RedneckwithGuns posted:

Now that just makes me want to go back and find the review paper I did on those types of extremophiles in undergrad. Friggin' bacteria in heavy metal mining waste that could make armor (proteinaceous shell) out of things like gold, lead, even a case where it happened with uranium.

Holy poo poo. I wish to subscribe to your newsletter, because that sounds amazing.

Sagebrush
Feb 26, 2012

ERM... Actually I have stellar scores on the surveys, and every year students tell me that my classes are the best ones they’ve ever taken.

McSpergin posted:

The site I'm working on at the moment has hectic environmental stuff. Like if there's a chemical spill (we only really use diesel and hydraulic oil on site being roadworks) on the alignment or any part of the site they have to stop work, remove the dirt until they find clean earth in all directions, go a bit further, then refill with clean earth. It can be painful like when there was a 200L oil spill the other week it cost us half a day all because a hose blew on a scraper

A number of years ago a family friend had their oil furnace line break loose inside their basement, and about ten gallons (40L) of diesel spilled into their basement. Turns out that if that happens to you, a Really Good Idea is to keep quiet about it and soak it up yourself with kitty litter, because if you call in the pros it turns out that they have to do this same thing. In my friends' case they had to excavate about a 10-foot-square chunk of their basement floor down to 6 feet, haul all the earth out in buckets, and treat it as toxic waste. Cost something like $20,000 all-up.

Memento
Aug 25, 2009


Bleak Gremlin
Probably of interest to a lot of people in this thread.

babyeatingpsychopath
Oct 28, 2000
Forum Veteran


Memento posted:

Probably of interest to a lot of people in this thread.

I saw the picture. Curious. Saw the tags, CRINGED.

Saw that it was actual real plutonium, and had to read further to prove that one of those didn't roll, go critical, and then cause the photographer to puke up all their white blood cells and die.

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Double Punctuation
Dec 30, 2009

Ships were made for sinking;
Whiskey made for drinking;
If we were made of cellophane
We'd all get stinking drunk much faster!

babyeatingpsychopath posted:

I saw the picture. Curious. Saw the tags, CRINGED.

Saw that it was actual real plutonium, and had to read further to prove that one of those didn't roll, go critical, and then cause the photographer to puke up all their white blood cells and die.

The article says there's probably not enough to go critical. "Probably" being the key word here.

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